plutonium-induced health effects are considered to be the result of energy deposited by alpha particle emissions in tissues that retain plutonium for extended periods (i.e., lung, bone, liver following inhalation exposure). Similar health effects would be expected from any alpha-emitting source that would result in similar cumulative tissue-specific radiation dose and dose rate.
They seem fairly certain that it is alpha particle damage, not chemistry.
What do you mean "decay chains"? Po-210 decays to Pb-206 which is stable. So you mean Po-210 decay. Let's shut down the chemical industry because someone attempted to poison The Skripals. https://en.wikipedia.org/wiki/Poisoning_of_Sergei_and_Yulia_... .
> medical mistakes
Spent nuclear fuel is generally not used for medical isotopes. They specially prepare samples for irradiation to not have to use reprocessing, e.g. https://en.wikipedia.org/wiki/Cobalt-60#Production .
> I could have a look for you
It would be illuminating to see what you find reasonable.