<% , %>. This is only one that looks symmetric
Less-modern trigraphs: ??< , ??>
Unix v4 (in the teletype driver): \( , \)
PDP-11 B: *( , *)
PDP-7 B: $( , $)
In other micro software (Advanced MuMath for the TRS-80), I have seen: << , >> for [ , ]
(< , >) for { , }
Back in the 80's, the joke among new learners of C and Unix is that the designers must have had a very bad keyboard where typing each character was painful, because every keyword or command was so short and cryptic. This article suggests a different reason: on their 36-bit Honeywell 6070, "four characters fit into a word", so there was incentive to fit in 1 machine word.
I also read that a few Chinese texts only make sense in vertical order: one had a pun where the characters read one way as separated characters, but as stacked was also a single character pun for something like a "crumbly cookie".