Starting Strength and only primarily targets the ability to lift heavy objects. On its own it does nothing to improve your cardio fitness and it doesn't directly help with postural problems or injury prevention. And if your
main interest is in gaining muscle and looking better, there are much better routines. In all the gyms I've been to, I've yet to see a big guy who was doing a stripped down strength focused routine... Finally, it also has to be noted that many people do not have good experiences with the big barbell exercises, especially if they have pre-existing issues with their knees/back/shoulders, even if they use good form.