Yes, at least in Poland. You can either use Blik (mobile payments integrated with your bank account) or get redirected to your bank website for fast wire transfer.
From personal experience, it doesn't work that well. The available 3D models [1] are not detailed enough and the effort to make realistic and diverse renders is huge. It will kinda work but it won't generalize well into real images.
RebrickNet is an abandoned project that supports only 300 parts. I recommend Brickognize [1], which recognizes all 85k Lego parts, minifigures, and sets.